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Organic solvent system may

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"In semiconductor production, people want to avoid having a metal catalyst remaining in devices, but in many cases, they cannot use existing water-based processes because these can damage the semiconductor oxides and introduce contamination with free ions in the aqueous solution," explained Wei Lin, a graduate research assistant in Wong's laboratory. "Use of this organic system avoids the problem of moisture."

Use of the selective process could also facilitate recycling of noble metals used in electronics manufacturing. Wire-bonding, metallization and interconnect processes currently use noble metals.

Noble metals are also the foundation for widely-used chemotherapy agents, but the chemistry of synthesizing them involves a complex process of surfactants and precursors. Wong believes the new Georgia Tech solvent process may allow creation of novel with battery such as Panasonic CGA-S101A Battery , Olympus Li-10B Battery , Olympus BLM1 Battery , panasonic NV-GS10 battery , panasonic VHS-C Battery , canon EOS 400D Battery , panasonic VW-VBD1E Battery , panasonic VW-VBD1 Battery , Panasonic CGA-S002 Battery , HITACHI DZ-HS300E Battery , Olympus FE-230 Battery , canon MV930 Battery compounds that could offer improved therapeutic effects.

Wei Lin holds a gold/organic aqua regia solution. The image on the monitor shows gold recovered from the solution using calcinations. Credit: Credit: Gary Meek

"We hope this will open up some new ways of making these important pharmaceutical compounds as well as novel gold and palladium catalytic systems," he said.

Lin discovered the new solvent system by accident in 2007 while using thionyl chloride in an unrelated project that involved bonding carbon nanotubes to a gold substrate. "I left my sample in the solution and went to lunch," he recalled. "Then I received a couple of phone calls and the sample stayed in the solution for too long. When I got it out, the gold was gone."

The researchers were intrigued by the discovery and pursued an explanation as they had time over the past three years. They tested other reagents mixed with the thionyl chloride, and learned the proportions necessary for selective dissolution of palladium and gold. They worked with other researchers at Georgia Tech, including nanotechnology pioneer Zhong Lin Wang, to develop a fundamental understanding of the process – research that is continuing.

The chemicals used by the Georgia Tech research team are well known in organic chemistry, and are used today in polymer synthesis. Beyond their selectivity, the new solvent system is more environmentally friendly than traditional aqua regia – which is a combination of concentrated nitric and hydrochloric acids – and can operate at mild conditions. Potential disadvantages compared to traditional aqua regia include higher costs and slower dissolution rates.

"We have opened up a new approach to noble metals using organic chemistry," Wong added. "We don't yet thoroughly understand the mechanism by which this works, but we hope to develop a more complete understanding that may lead to additional applications."